Arsenic Removal with Alumina

Ian Elliott: elliotti@onid.orst.edu

Wallace Brown: brownwa@onid.orst.edu

Nick Zachman: zachmann@onid.orst.edu

 

 

 

 

Motivation

•         Groundwater contamination in Bangladesh and other nations

•         19% of wells in Bangladesh contaminated

•         Typical Arsenic contamination is 300 ppb

Facts about Arsenic

•         Arsenic is a poison and its lethal dose for a human is 125 milligrams

•         It is 4 times as poisonous as mercury

•         Almost all organs are affected by arsenic

•         Side effects include: cancer, melanosis, liver enlargement, and hearing loss

•         In nature, there is plenty of arsenic

•         Arsenic is present in air, soil and water

•         U.S. standards for safety are 50 ppb or less

 

Procedure

•         25 mL Arsenic solution with known alumina mass

•         Shaken and analyzed at various times

•         Centrifuge to separate and recover Alumina

Results

•         Removes above 80% of Arsenic in an hour

•         Removal rate plateaus after an hour

•         One gram of Alumina will treat 10 Liters of 300 ppb drinking water

 

 

Equipment

•         ICP (Inductively Coupled Plasma) AES used to detect Arsenic concentration

•         Experiment conducted in centrifuge tube with 25 mL of solution

 

Limitations

•         Experiments performed at higher concentrations than are present in groundwater

•         Analytical equipment could not accurately read Arsenic concentrations below 300 ppb

Future Plans

•         Test Alumina pellets of varying surface area

•         Develop a flow through system

•         Test the Alumina’s ability to remove As(III)

•         Test the possibility of regenerating the used Alumina pellets.

 

Special Thanks To

•         Dr. Mohammad Azizian

•         Dr. Alex Yokochi

•         Dr. David Hacklemann

•         The Hanso Foundation